1000 ml =
0.001 m2
17407.9 N/m2.ml
= 0.01741 N/m2 * m3 = 0.01741 J
|
|
Quantity
|
|
Atmospheric
pressure
|
94,628.8
N/m2
|
|
Area
of piston
|
1.709
* 10 –4 m2
|
|
Mass
of piston
|
0.016
kg
|
|
Work
(m*g*h)
|
19.6
* 10-3 J
|
|
Work
(area under the parallelogram)
|
17.41
* 10 –3 J
|
|
%
Difference
|
11.2
%
|
CALCULATIONS:
Diameter
of piston = 1.475 cm
100
cm = 1 m
1.475
cm = (1.475 cm * 1 m) /* 100 cm = 1.475 * 10–4 m2
Area of piston = pr2
= p
(7.375 * 10-3) 2 = 1.709 * 10-4 m2
Atmospheric pressure = 710 mm Hg
1mm Hg = 1.333 * 102 N/m2
710 mm Hg = (710 mm Hg * 1.333 * 102
N/m2) / 1 mm Hg = 94,643 N/m2
Pressure = Force / Area
Pressure
of the system at A:
(0.016 kg * 9.8 m/s2)
/ (1.709 * 10-4 m2) = 917.49 N/m2
917.49
N/m2 + atmospheric pressure = 95560.49 N/m2
Pressure of the system at B:
A
mass is added to the system, pressure increases:
(0.016 kg + 0.05 kg) * 9.8 m/s2
/ (1.709 * 10-4
m2) = 3,784.67 N/m2
3,784.67
N/m2 + atmospheric pressure = 9,8427.67 N/m2
Pressure
of the system at C:
Same
as pressure at B
(0.016 kg + 0.05 kg) * 9.8 m/s2
/ (1.709 * 10-4
m2) = 3,784.67 N/m2
3,784.67
N/m2 + atmospheric pressure = 9,8427.67 N/m2
Pressure
of the system at D:
Same
as pressure at A
(0.016
kg + 0.05 kg) * 9.8 m/s2 / (1.709 * 10-4
m2)
= 3,784.67 N/m2
3,784.67
N/m2 + atmospheric pressure = 9,8427.67 N/m2
Work
done to move the piston = m*g*h
H = D
volume / Area
(7.2
* 10-6 m3 – 0.8 * 10-6 m3)
/ (1.709 * 10-4 m2) = (6.4 * 10-6 m3)
=
(6.4 * 10-6 m3) / (1.709 * 10-4
m2) = 0.0375 m
»0.04
m
WORK
= 0.05
kg * 9.8 m/s2 * 0.04 m = 0.0196 J
=
19.6 * 10-3 J
% Difference
between work (m*g*h) and work (area of rhombus)
(2.2
* 10-3 J) / (19.6 * 10-3 J) * 100% = 11.2 %
Conclusion:
The large
percentage difference indicates that there were some errors made in the
experiment. These errors could have been made when obtaining the different
volumes of the syringe, when measuring the diameter of the plunger etc.However,
the experiment was a success in that we were able to study and understand
the three different gas laws (Guy Lussac’s Charles and Boyle’s) as well
as apply the principles of each to the construction of a thermodynamic
cycle, which we were able to use for work.